Title: The reaction of formic acid with Raney TM copper

Authors (5): S. K. Callear, I. P. Silverwood, A. Chutia, C. R. A. .Catlow, S. F. Parker

Themes: Design (2016)

DOI: 10.1098/rspa.2016.0126

Citations: 3

Pub type: article-journal

Publisher: The Royal Society

Issue: 2188

License:

Publication date(s): 2016/04/30 (print) 2016/04 (online)

Pages: 20160126

Volume: 472 Issue: 2188

Journal: Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences

Link: https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.2016.0126

URL: http://dx.doi.org/10.1098/rspa.2016.0126

The interaction of formic acid with RaneyTM Cu proves to be complex. Rather than the expected generation of a monolayer of bidentate formate, we find the formation of a Cu(II) compound. This process occurs by direct reaction of copper and formic acid; in ...

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