Title: Room temperature methoxylation in zeolite H-ZSM-5: an operando DRIFTS/mass spectrometric study

Authors (4): S. K. Matam, R. F. Howe, A. Thetford, C. R. A. .Catlow

Themes: Design (2018)

DOI: 10.1039/c8cc07444e

Citations: 26

Pub type: article-journal

Publisher: Royal Society of Chemistry (RSC)

Issue: 91

License: http://creativecommons.org/licenses/by/3.0/

Publication date(s): 2018 (online)

Pages: 12875-12878

Volume: 54 Issue: 91

Journal: Chemical Communications

Link: http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07444E

URL: http://dx.doi.org/10.1039/C8CC07444E

At high loading, methanol reacts under ambient conditions with acidic hydroxyls of H-ZSM-5 to methoxylate framework oxygen; while a significant proportion remains hydrogen bonded to the framework with protonated geometry.

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c8cc07444e1.pdf Supl. data for Room temperature methoxylation in zeolite H-ZSM-5: an ope... 2018


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