Title: The Role of Mg(OH)2 in the So-Called “Base-Free” Oxidation of Glycerol with AuPd Catalysts

Authors (8): J. Fu, Q. He, P. J. Miedziak, G. L. Brett, X. Huang, S. Pattisson, M. Douthwaite, G. J. Hutchings

Themes: Environment (2018)

DOI: 10.1002/chem.201704151

Citations: 24

Pub type: article-journal

Publisher: Wiley

Issue: 10

License: http://doi.wiley.com/10.1002/tdm_license_1.1

Publication date(s): 2018/02/16 (print) 2018/01/24 (online)

Pages: 2396-2402

Volume: 24 Issue: 10

Journal: Chemistry - A European Journal

Link: https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201704151

URL: http://dx.doi.org/10.1002/chem.201704151

No base required: AuPd converts glycerol into acid products that can decrease the pH of the reaction solution and then inhibit the reaction without the need for extra base. When Mg(OH)2, a sacrificia...

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