Publisher: Royal Society of Chemistry (RSC)

Issue: 44

License: http://rsc.li/journals-terms-of-use

Publication date(s): 2017 (online)

Pages: 15157-15174

Volume: 46 Issue: 44

Journal: Dalton Transactions

Link: http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03395H

URL: http://dx.doi.org/10.1039/C7DT03395H

Diphosphorus ligands connected by a single atom (R₂PEPR₂; E = CR₂, C\ue001CR₂and NR) give chelating ligands with very small bite-angles as well as enable access to other properties such as bridging modes and hemilability. ThisPerspectivereviews the properties of diphosphorus ligands featuring a single-atom linker and their applications in catalysis, including transformations of alkenes and transfer hydrogenation and hydrogen-borrowing reactions.

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