Title: Heterodinuclear zinc and magnesium catalysts for epoxide/CO2 ring opening copolymerizations

Authors (3): G. Trott, J. A. Garden, C. K. Williams

Themes: Transformations (2019)

DOI: 10.1039/c9sc00385a

Citations: 120

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue: 17

License: [{"start"=>{"date-parts"=>[[2019, 3, 26]], "date-time"=>"2019-03-26T00:00:00Z", "timestamp"=>1553558400000}, "content-version"=>"vor", "delay-in-days"=>84, "URL"=>"http://creativecommons.org/licenses/by-nc/3.0/"}]

Publication date(s): 2019/04/24 (print) 2019 (online)

Pages: 4618-4627

Volume: 10 Issue: 17

Journal: Chemical Science

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00385A", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/c9sc00385a

Eight heterodinuclear catalysts comprising Zn(ii) and Mg(ii) metal centres show high activity and selectivity for CO2/epoxide ring-opening copolymerization. Detailed kinetic analyses are reported and a chain-shuttling mechanistic hypothesis proposed.

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