Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst
Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst
Authors (8): I. B. Minova, M. Bühl, S. K. Matam, C. R. A. Catlow, M. D. Frogley, G. Cinque, P. A. Wright, R. F. Howe
Themes: New Catalysts
DOI: 10.1039/d1cy02361f
Citations: 13
Pub type: journal-article
Pub year: 2022

Publisher: Royal Society of Chemistry (RSC)

Issue:

License: [{"start"=>{"date-parts"=>[[2023, 2, 21]], "date-time"=>"2023-02-21T00:00:00Z", "timestamp"=>1676937600000}, "content-version"=>"am", "delay-in-days"=>416, "URL"=>"http://rsc.li/journals-terms-of-use"}]

Publication date(s): 2022 (online)

Pages:

Volume: Issue:

Journal: Catalysis Science & Technology

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02361F", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d1cy02361f

In situ synchrotron infrared microspectroscopy on single crystals of SAPO-34 reveals that a carbene insertion mechanism is responsible for the first carbon–carbon bond formation from surface methoxy groups.

Name Description Publised
Carbene-like Reactivity of Methoxy Groups in a Single Crystal SAPO 34 MTO Catalyst (dataset) Data availabilityThe research data supporting this publication can be ac... 2022
d1cy02361f1.pdf Supl. data file (document)... 2022


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