Publisher: Royal Society of Chemistry (RSC)

Issue: 41

License: [{"start"=>{"date-parts"=>[[2023, 9, 22]], "date-time"=>"2023-09-22T00:00:00Z", "timestamp"=>1695340800000}, "content-version"=>"am", "delay-in-days"=>629, "URL"=>"http://rsc.li/journals-terms-of-use"}]

Publication date(s): 2022/10/25 (print) 2022 (online)

Pages: 15783-15791

Volume: 51 Issue: 41

Journal: Dalton Transactions

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02888C", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d2dt02888c

1,8-C10H6(BCat)(BMes2) takes up F− to give a kinetic product featuring a bridging B–F–B unit. An alternative structural motif featuring a terminal B–F bond and a B–O–B bridge using one of the catechol oxygens is shown to be more favourable thermodynamically.