Title: Mechanism of ammonia synthesis on Fe3Mo3N

Authors (4): M. Higham, C. D. Zeinalipour-Yazdi, J. S. J. .Hargreaves, C. R. A. .Catlow

Themes: New Catalysts (2023)

DOI: 10.1039/d2fd00148a

Citations: 3

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue:

License: [{"start"=>{"date-parts"=>[[2022, 11, 25]], "date-time"=>"2022-11-25T00:00:00Z", "timestamp"=>1669334400000}, "content-version"=>"vor", "delay-in-days"=>0, "URL"=>"http://creativecommons.org/licenses/by/3.0/"}]

Publication date(s): 2023 (online)

Pages:

Volume: Issue:

Journal: Faraday Discussions

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2023/FD/D2FD00148A", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d2fd00148a

The novel Eley–Rideal–Mars–van-Krevelen mechanism for ammonia synthesis on Fe3Mo3N relies on the presence of surface lattice N vacancies and proceeds through the intermediate.

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